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1 article(s) from Li, Dong-Hao

Molecular recognition using tetralactam macrocycles with parallel aromatic sidewalls

Dong-Hao Li and
Bradley D. Smith

Beilstein J. Org. Chem. 2019, 15, 1086–1095, doi:10.3762/bjoc.15.105

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Graphical Abstract

Scheme 1: Chemical structures of the tetralactam host macrocycles that are covered by this review.

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Figure 1: X-ray crystal structures of various squaraine rotaxanes show that the macrocycle bridging units con...

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Figure 2: X-ray crystal structures of macrocycles that are representative of the tetralactam systems in Scheme 1. In ...

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Scheme 2: Synthetic yields of [2]rotaxanes with different dumbbell-shaped templates and tetralactam A as the ...

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Scheme 3: Supramolecular picture of the amide-bond-formation step that clips tetralactam A around a biscarbon...

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Figure 3: Selected X-ray structures of [2]rotaxanes with tetralactam A as the surrounding macrocycle reported...

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Figure 4: (a) Chemical structures of squaraine, thiosquaraine, croconaine, and acene guests that can bind ins...

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Scheme 4: Complex stabilization due to guest back folding and aromatic stacking with the surrounding tetralac...

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Figure 5: (a) Shape and electrostatic comparison of squaraine C₄O₂ core (left) with anionic square planar met...

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Figure 6: Chemical structures of a) acetylcholine chloride, 26⁺·Cl⁻, (b) trimethyl-p-cyanobenzylammonium chlo...

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Figure 7: a) Chemical structure of β-D-glucopyranose and the solid-state structure of its complexes with macr...

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Published 09 May 2019

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